The free radical polymerization of vinyl acetate was performed in the presence of deuterated chloroform cdcl 3 as a chain transfer agent telogen and 2 2 azobisisobutyronitrile as an initiator the effects of the initiator and solvent. Branching in free radical polymerization due to chain. We first studied the monomer size effect on free radical polymerization by using vinyl esters with different molecular dimensions length width i e vinyl acetate vac 5 9 4 0 å 2 vinyl propionate vpr 6 4 4 0 å 2 2.
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